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第1集
Ryan takes charge of Division with Nikita by his side. Their first mission under the new regime is to bring in “The Dirty Thirty,” the rogue agents who failed to respond to the Division recall after Percy was killed. Unfortunately, their first mission doesn’t go as planned and Michael is arrested, forcing Nikita to change gears and hatch an escape plan for him. Alex reprises her alter ego, the spoiled Russian princess Alexandra Udinov, in a very unique way as part of the plan to spring Michael. Meanwhile, Birkhoff struggles to maintain a working relationship with Sonya, despite his growing attraction to her.
2、 纯真
Nikita, Michael and team extract a young girl named Liza, who is being held captive by a rogue Division agent, Wade. Wade has brainwashed Liza and trained her to be a Division agent to help him on his own personal mission. Nikita tries desperately to break through to Liza but, in a moment of chaos, the girl escapes Division. The team races to find her before she can complete her mission to unleash a deadly chemical into the UN building during a special event. Meanwhile, Liza’s abduction brings up painful old memories for Alex.
3、 真正的信徒
When Ryan tells Nikita an undercover agent has been arrested and they need to extract her from prison, Nikita questions why Division is continuing to run Percy’s old missions. Nikita, Michael and Sean attempt to stop a terrorist attack but are one man down after Alex is shot. Meanwhile, Birkhoff and Sonia continue to bicker.
4、 后果
Amanda sends a rogue Division agent, Anne to spring Owen from a Russian prison, but Owen manages to escape her clutches and sends a message to Nikita that he’s free. When Nikita tracks him down, Owen is shocked to learn that Nikita is with Division now but returns to base with her. Michael and Ryan aren’t sure they can trust Owen but Nikita stands by her friend.
5、 剑刃
组织发现潜伏了六年的叛逃特工Markov竟然被选为乌兹别克斯坦总统，而且正计划杀害美国总统。众人要求Ryan立刻通知总统加强安全保卫，Ryan这才说出实情：这位女总统对组织早已深恶痛绝，要不是Ryan竭力阻止，只怕她早就下令铲除组织了。Nikita和Michael对Ryan长期隐瞒这个重要秘密颇为愤怒，现在他们只能想办法暗中保护总统的安全，同时又不惊动她。另一方面，Alex和Owen遭遇一次爆炸事故但侥幸逃生。他们怀疑这是组织的内鬼所为，决定联手展开调查。
6、 侧击
Nikita and Michael capture Cyrus, an arms dealer, who is purchasing a weapon-jamming device for Ari. Nikita convinces Ryan to let them use Cyrus as bait to capture Amanda but Cyrus manages to escape the trap. However, when Amanda double crosses Cyrus, his only hope for survival is Nikita. Meanwhile, Birkhoff is hot on the trail of Amanda’s mole and Alex starts to unravel.
7、 路口
Birkhoff tells Nikita that Sonya is Amanda’s mole and not only has Amanda reactivated Sonya’s kill chip but she also placed a second mole in Division to keep an eye on her. Nikita, Michael and Ryan devise a plan to use Sonya to ferret out Amanda’s hiding place and Birkhoff sets a trap for the second mole. Meanwhile, Michael confronts Alex about her drug use and she begs him not to tell Nikita.
8、 善后
Nikita and Owen face off against a rogue “cleaner” named Liam, while Michael takes a new position at Division. Michael and Nikita’s relationship becomes strained as he watches her work with Owen.
9、 生存本能
叛逃特工Ray绑架了自己的女友Kate，于是Ryan派遣Nikita带领一支行动组前去施救。Michael自己没有来，而是把Owen派来了，这让Nikita颇为疑惑。与此同时，Sean做出一个与Alex有关的决定。
10、 美丽新世界
Michael gives up his role as a field agent and resumes his role inside Division running Operations. After learning key information from Birkhoff, Nikita preps a secret mission that takes her into dangerous territory. When Michael and Alex and Ryan find out, they follow her into Kosovo but the outcome has far-reaching consequences for Division.
11、 黑色徽章
中情局特工Naomi偶然发现了一份记录Madeline Pierce与组织的关系的绝密文件，立即将它呈交给中情局局长Morgan Kendrick。Kendrick不久后遭到暗杀，Amanda陷害Sean是杀人凶手，中情局立刻派人将他羁押。Nikita向心急如焚的Alex保证，他们一定能把Sean就出来。但是Nikita的计划风险极大——Sean要么获救，要么命丧当场。
12、 用火
After Birkhoff gets a tip from Shadowbot that Ari is in NY, Nikita and Owen swoop in to pick him up before the FBI does. However, Ari reveals he planned everything for a chance to talk to Nikita. He tells her that Amanda has gone too far and is working with a terrorist who plans an attack on American soil. Ari wants fifty million dollars for the information that could lead to the terrorist’s capture. Nikita and Michael are stunned when Ryan considers paying the bribe. Meanwhile, Sean is jealous of Alex and Owen’s relationship.
13、 团圆
In order to gain control of the black box, Amanda makes plans to kidnap Ari's son Stefan (Dylan Minnette) to use him as leverage. Still in Division’s protective custody, Ari begs Nikita for help. However, Stefan’s bodyguard Krieg (Andrew Divoff) manages to capture both Nikita and Amanda and the two must work together to escape. Owen is furious with Michael after Michael assigns Alex to be Nikita’s back-up instead of him.
14、 我们选择的生活
Amanda holds Alex hostage and tells Nikita she will release Alex in exchange for Ari. Michael assigns Nikita and Sean to handle the exchange of prisoners, but Ryan adds Owen to the team at the last minute, which makes Michael suspicious. While in captivity, Alex befriends a fellow prisoner named Larissa and vows to break them both out of the jail, which ultimately conflicts with Nikita’s plan, forcing Alex to choose between Nikita and her promise to Larissa.
15、 必然性
When Nikita decides Division should take on a government mission to eliminate the President of Chad while he’s in Paris, Alex takes a stand and refuses to participate. Upset that Nikita is keeping secrets from everyone, much like Percy did, Alex recruits Birkoff to dig up secrets on Danforth to use as leverage in case things get messy with the government. Alex and Birkhoff are shocked when they come across a secret so big it could blow up Division — literally.
16、 临界点
Nikita and Michael learn of a new prosthetic hand that could have Michael back to his old self, but it comes at a steep price. Meanwhile, Alex and Sean are tasked with investigating who, inside Division, is behind a mutiny that ends in bloodshed.
17、 面具
Alex confesses her desire to leave Division to Birkhoff, while Amanda begins providing Owen with something he was never able to find – memories of his real past. Despite Nikita’s attempts to help, Owen begins to confront the events of his past.
18、 破碎家庭
Strapped down and drugged, Nikita is subjected to Amanda's horrific mental conditioning process, sending her down a terrible trip through memory lane. In the process, Nikita discovers Amanda's deepest, most guarded secret ever. Now revealed as leader of the uprising, Alex struggles to save everyone as events violently escalate. With Michael locked away by Division conspirators, Birkhoff and Sean must step up to save the women they love. Meanwhile, Owen's newfound memories drive him to disturbing actions during Division's lockdown.
19、 自毁
对Amanda洗脑的惧怕、对无力拯救每一个人的负罪感和对上集发生的悲剧事件的责任感让Alex彻底崩溃，她又走上了老路，并且以极其暴力的方式来发泄。组织里许多人要么死了，要么受伤了，要么失散了，要么心灵遭受了严重创伤，Nikita和Michael必须评估损失并竭尽全力从废墟上重建家园。但是他们的行动必须迅速——如果总统知道了这里发生的事情，或许组织就彻底完了。当Nikita和Michael坐下来唏嘘往事，回忆组织最辉煌的过去时，Birkhoff也在为自己的损失而伤感。
20、 高价值目标
听命于Amanda的一个叛变特工从组织的废墟中找到了黑盒子，将其交给了主人。不久之后，黑盒子里的部分信息遭到泄露，显然Amanda在向潜在的国际买家投石问路，希望能借此提高黑盒子的卖价。在没有支援团队，没有任何线索，时间又非常紧迫的情况下，剩余的组织成员必须拼尽全力来阻止Amanda的邪恶计划。幸运的是，改过自新的叛徒、军火贩子Cyrus在关键时刻出现，承诺给予他们一切帮助。有了Cyrus的帮助，Nikita、Michael和Alex策划了一个大胆的行动——他们要利用戒备森严的二十国集团竞技峰会夺回黑盒子，同时修正已经被Amanda改写的人生命运。
21、 看不见的手
终于，在订婚之前，Nikita曾说总是会有另一项任务。从最近的一系列事件中侥幸逃生后，Michael不禁开始怀疑Nikita对婚姻的忠诚——脱离了组织，脱离了无休无止的欺骗、背叛和谋杀，他们会有美好的未来吗？Nikita愿意和他一起过平静的生活吗？显然Michael不是唯一持怀疑态度的人。不过来自Amanda的威胁仍然没有解除，尤其是她现在有了神秘的新盟友，他们向她提供了一件可怕的新武器。与此同时，Alex奉命保护一名诺贝尔奖获得者，他提出一个让Alex心动的提议。
22、 至死方休
在季终集里，Amanda将Nikita逼入绝境，迫使她在救Michael和救自己之间做出选择。众人争分夺秒阻止Amanda的邪恶计划，但在缺少组织资源的情况下，他们无论人手、装备还是技术都占下风。
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